Issue 22, 2001

The tetramethylpiperidinyl-1-oxide anion (TMPO) as a ligand in lanthanide chemistry: synthesis of the per(TMPO) complex [(ONC5H6Me4)2Sm( μ-ONC5H6Me4)]2

Abstract

(C5Me5)3Sm reacts with the free radical 2,2,6,6-tetramethylpiperidinyl-1-oxy (TMPO) to form (C5Me5)2 and the per nitroxide [(η1-ONC5H6Me4)2 Sm(μ-η1∶η2-ONC5H 6Me4)]2

Supplementary files

Article information

Article type
Communication
Submitted
28 Jul 2001
Accepted
14 Sep 2001
First published
25 Oct 2001

Chem. Commun., 2001, 2326-2327

The tetramethylpiperidinyl-1-oxide anion (TMPO) as a ligand in lanthanide chemistry: synthesis of the per(TMPO) complex [(ONC5H6Me4)2Sm( μ-ONC5H6Me4)]2

W. J. Evans, J. M. Perotti, R. J. Doedens and J. W. Ziller, Chem. Commun., 2001, 2326 DOI: 10.1039/B106869P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements